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Photo of Andrei Sanov(sanov)

Andrei Sanov

Professor, Chemistry and Biochemistry-Sci,
Professor, Chemistry and Biochemistry - Med,
Member of the Graduate Faculty,
Professor, Physics,

Chemistry & Biochemistry - Sci
sanov@arizona.edu
520/626-8399
UAVitae logogoogle scholar logoOrcid logo
Grant: $1.8M
Andrei Sanov experts in condensed matter physics, physical chemistry, spectroscopy, chemistry, inorganic chemistry, photochemistry, theoretical chemistry, physics, organic chemistry, molecular beam epitaxy, materials science, condensed matter theory, molecular spectroscopy, astrophysics, atomic physics, quantum optics, molecular interferometry, photoelectron spectroscopy, nanophotonics, plasmonics, particle physics, environmental chemistry, atmospheric chemistry, molecular imaging, biomedical optics, quantum chemistry, bioinorganic chemistry, polymer chemistry
Courses
Introduction to Quantum Chemistry 
Mathematical Methods for Chemists 
Mathematical Physics for Chemistry 
Quantum Chemistry 
Physical Chemistry 
General Chemistry Lecture I: Quantitative 
General Chemistry Lecture II: Quantitative Approach 
Recent Grants
Logo of Molecular Networks: Bonding and Long-Range Interactions in Anionic Environments funding agency
2022 $474.7KActive
Molecular Networks: Bonding and Long-Range Interactions in Anionic Environments
Logo of Chemical Bonding Via Anion Photoelectron Imaging Spectroscopy funding agency
2017 $413.2K
Chemical Bonding Via Anion Photoelectron Imaging Spectroscopy
Logo of Structure and Photoemission Dynamics of negative ions via Photoelectron Imaging Spectroscopy funding agency
2013 $413.2K
Structure and Photoemission Dynamics of negative ions via Photoelectron Imaging Spectroscopy
Logo of Structure and Dynamics of Molecular and Cluster Anions Via Photoelectron Imaging Spectroscopy funding agency
2010 $518.8K
Structure and Dynamics of Molecular and Cluster Anions Via Photoelectron Imaging Spectroscopy
News
2015UA Researchers Reveal Elusive Molecule  
2008Luis Velarde Awarded University of California's Presidential Postdoctoral Fellowship 
2002UA Chemist Andrei Sanov Wins Arnold and Mabel Beckman Young Investigator Award 
Publications (120)
Recent
2022Photoelectron Spectra of Hot Polyatomic Ions: A Statistical Treatment of Phenide 
2022Dipole effects in the photoelectron angular distributions of the sulfur monoxide anion 
2022Velocity map imaging spectroscopy of C2H− and C2D−: A benchmark study of vibronic coupling interactions 
2021Anion of Oxalyl Chloride: Structure and Spectroscopy 
2021Diradical Interactions in Ring-Open Isoxazole 
2021Weak covalent interactions and anionic charge-sharing polymerisation in cluster environments 
2021Photoelectron angular distributions in photodetachment from polarised d-like states: the case of HO2− 
2021Intermolecular interactions in cluster anions 
2020The quest to uncover the nature of benzonitrile anion 
2020Deprotonation of Isoxazole: A Photoelectron Imaging Study 
2019Photoelectron Spectroscopy of Biacetyl and Its Cluster Anions 
2017Electron affinity and excited states of methylglyoxal 
2016Anion photoelectron imaging spectroscopy of glyoxal 
2016HOCCO versus OCCO: Comparative spectroscopy of the radical and diradical reactive intermediates 
2015Spectroscopy of Ethylenedione 
2015Benzonitrile: Electron affinity, excited states, and anion solvation 
2015Aromatic Stabilization and Hybridization Trends in Photoelectron Imaging of Heterocyclic Radicals and Anions 
2014Photochemistry of Fumaronitrile Radical Anion and Its Clusters 
2014Laboratory-Frame Photoelectron Angular Distributions in Anion Photodetachment: Insight into Electronic Structure and Intermolecular Interactions 
2014Heterogeneously Substituted Radicals and Carbenes: Photoelectron Imaging of the FC(H)CN- and FCCN- Anions 
2014Low-Lying Electronic States of Cyclopentadienone 
2014Cyanobenzyl and chlorobenzyl radicals via anion photoelectron imaging spectroscopy 
2014Spectroscopy of the breaking bond: the diradical intermediate of the ring opening in oxazole 
2014Photoelectron angular distributions for states of any mixed character: An experiment-friendly model for atomic, molecular, and cluster anions 
2013Photodetachment anisotropy for mixed s-p states: 8/3 and other fractions 
2013Selective deprotonation of oxazole and photoelectron imaging of the oxazolide anion 
2013Heterogeneous substitution effects in chlorocyanomethyl radical and chlorocyanocarbene 
2013Photoelectron angular distributions of pyridinide: A benchmark application of the mixed s-p model to a truly polyatomic anion 
2012Variable-temperature rate coefficients of proton-transfer equilibrium reaction C sub 2 /sub H sub 4 /sub + H sub 3 /sub O sup + /sup ↔ C sub 2 /sub H sub 5 /sub sup + /sup + H sub 2 /sub O measured with a coaxial molecular beam radio frequency ring electrode ion trap 
2012Variable temperature rate studies for the reaction H sub 3 /sub O sup + /sup + (C sub 2 /sub H sub 2 /sub ) sub 2 /sub measured with a coaxial molecular beam radio frequency ring electrode ion trap 
2012Oxygen cluster anions revisited: Solvent-mediated dissociation of the core O sub 4 /sub sup - /sup anion 
2012Variable temperature rate studies for the reaction H3O(+) + (C2H2)2 measured with a coaxial molecular beam radio frequency ring electrode ion trap 
2012Variable-temperature rate coefficients of proton-transfer equilibrium reaction C2H4 + H3O+ ⇄ C2H5+ + H2O measured with a coaxial molecular beam radio frequency ring electrode ion trap 
2012Oxygen cluster anions revisited: solvent-mediated dissociation of the core O4(-) anion 
2012Photoelectron spectroscopy and photochemistry of tetracyanoethylene radical anion in the gas phase 
2011O(-) + acetaldehyde reaction products: search for singlet formylmethylene, a Wolff rearrangement intermediate 
2011Solvation effects on angular distributions in H sup - /sup (NH sub 3 /sub ) sub n /sub and NH sub 2 /sub sup - /sup (NH sub 3 /sub ) sub n /sub photodetachment: Role of solute electronic structure 
2011Photoelectron imaging as a quantum chemistry visualization tool 
2011Solvation effects on angular distributions in H- (NH3)n and NH2(-) (NH3)n photodetachment: role of solute electronic structure 
2011Photoelectron spectroscopic study of the oxyallyl diradical 
2011Photoelectron angular distributions in negative-ion photodetachment from mixed sp states 
2011O sup - /sup + acetaldehyde reaction products: Search for singlet formylmethylene, a Wolff rearrangement intermediate 
2011Electronic states of thiophenyl and furanyl radicals and dissociation energy of thiophene via photoelectron imaging of negative ions 
2010Photodissociation of nitromethane cluster anions 
2010Electronic structure and spectroscopy of oxyallyl: A theoretical study 
2010Photoelectron imaging of NCCCN sup - /sup : The triplet ground state and the singlet-triplet splitting of dicyanocarbene 
2010Vibronic coupling in the superoxide anion: The vibrational dependence of the photoelectron angular distribution 
2010C-H bond dissociation energy of malononitrile 
2010Further evidence for resonant photoelectron-solvent scattering in nitrous oxide cluster anions 
2010IR spectroscopic characterization of the thermally induced isomerization in carbon disulfide dimer anions 
2010Photoelectron imaging of NCCCN(-): The triplet ground state and the singlet-triplet splitting of dicyanocarbene 
2010Photoelectron imaging of cyanovinylidene and cyanoacetylene anions 
2009Low-lying electronic states of CH sub 3 /sub NO sub 2 /sub via photoelectron imaging of the nitromethane anion 
2009Effects of isomer coexistence and solvent-induced core switching in the photodissociation of bare and solvated (CS sub 2 /sub ) sub 2 /sub sup - /sup anions 
2009Photodetachment, photofragmentation, and fragment autodetachment of [O sub 2n /sub (H sub 2 /sub O) sub m /sub ] sup - /sup Clusters: Core-anion structures and fragment energy partitioning 
2009Observation and characterization of the CH3S(O)CH- and CH3S(O)CH- x H2O carbene anions by photoelectron imaging and photofragment spectroscopy 
2009Photoelectron imaging: An experimental window into electronic structure 
2009The lowest singlet and triplet states of the oxyallyl diradical 
2009Laboratory observation of the valence anion of cyanoacetylene, a possible precursor for negative ions in space 
2009Low-lying electronic states of CH(3)NO(2) via photoelectron imaging of the nitromethane anion 
2009Effects of isomer coexistence and solvent-induced core switching in the photodissociation of bare and solvated (CS2)2(-) anions 
2008Solvation-induced cluster anion core switching from NNO2(-)(N2O)n-1 to O(-)(N2O)n 
2008Photoelectron imaging of negative ions 
2008Electron binding motifs in the (CS sub 2 /sub ) sub n /sub sup - /sup (n 4) cluster anions 
2008Solvation-induced cluster anion core switching from NNO 2- (N2 O) n-1 to O- (N2 O) n 
2008Electron binding motifs in the (CS2)n- (n 4) cluster anions 
2008Relaxation of (CS sub 2 /sub ) sub 2 /sub sup - /sup to its global minimum mediated by water molecules: Photoelectron imaging study 
2008Relaxation of (CS2)2(-) to its global minimum mediated by water molecules: photoelectron imaging study 
2007Solvent resonance effect on the anisotropy of NO(-)(N(2)O)(n) cluster anion photodetachment 
2007Solvent resonance effect on the anisotropy of N O- (N2 O)n cluster anion photodetachment 
2007Photodissociation of CO2 - in water clusters via Renner-Teller and conical interactions 
2007Photodissociation of CO sub 2 /sub sup - /sup in water clusters via Renner-Teller and conical interactions 
2007Chemistry: Coherence and symmetry breaking at the molecular level 
2006Photoelectron imaging study of the effect of monohydration on O sub 2 /sub sup - /sup photodetachment 
2006Photoelectron imaging study of the effect of monohydration on O2 - photodetachment 
2006Photodetachment and photofragmentation pathways in the [(CO2)2(H2O)m]- cluster anions 
2006Solvent-enabled photodissociation of CO sub 2 /sub sup - /sup in water clusters 
2006Photodetachment and photofragmentation pathways in the [(CO sub 2 /sub ) sub 2 /sub (H sub 2 /sub O) sub m /sub ] sup - /sup cluster anions 
2005Photoelectron anisotropy and channel branching ratios in the detachment of solvated iodide cluster anions 
2005Dynamic molecular interferometer: Probe of inversion symmetry in I sub 2 /sub sup - /sup photodissociation 
2005Time-resolved imaging of the reaction coordinate 
2005Dynamic molecular interferometer: probe of inversion symmetry in I2(-) photodissociation 
2005Photoelectron imaging of hydrated carbon dioxide cluster anions 
2004Time-resolved electron detachment imaging of the I sup - /sup channel in I sub 2 /sub Br photodissociation 
2004Effects of solvation and core switching on the photoelectron angular distributions from (CO2)n(-) and (CO2)(n)(-).H2O 
2004Effects of solvation and core switching on the photoelectron angular distributions from (CO sub 2 /sub ) sub n /sub sup - /sup and (CO sub 2 /sub ) sub n /sub sup - /sup ·H sub 2 /sub O 
2004Cluster anions: Structure, interactions, and dynamics in the sub-nanoscale regime 
2004Time-resolved electron detachment imaging of the I- channel in I2Br- photodissociation 
2003Imaging of direct photodetachment and autodetachment of (OCS)2-: excited-state dynamics of the covalent dimer anion 
2003Photoelectron imaging of negative ions: atomic anions to molecular clusters 
2003An experimental manifestation of distinct electronic-structural properties of covalent dimer anions of CO sub 2 /sub and CS sub 2 /sub 
2003Imaging of direct photodetachment and autodetachment of (OCS) sub 2 /sub sup - /sup : Excited-state dynamics of the covalent dimer anion 
2003Probing the electronic structure of small molecular anions by photoelectron imaging 
2003Photoelectron imaging of carbonyl sulfide cluster anions: Isomer coexistence and competition of excited-state decay mechanisms 
2002Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase hydration 
2002Photoelectron imaging spectroscopy of molecular and cluster anions: CS sub 2 /sub sup - /sup and OCS sup - /sup (H sub 2 /sub O) sub 1,2 /sub 
2002Dynamics of cluster anions: A detailed look at condensed-phase interactions 
2001Competitive pathways via nonadiabatic transitions in photodissociation 
1999Spin-orbit relaxation and recombination dynamics in I sup - /sup sub 2 /sub (CO sub 2 /sub ) sub n /sub and I sup - /sup sub 2 /sub (OCS) sub n /sub cluster ions: A new type of photofragment caging reaction 
1999Spin-orbit coupling in I·CO sub 2 /sub and I·OCS van der Waals complexes: Beyond the pseudo-diatomic approximation 
1999Photoinitiated decomposition of HNCO near the H+NCO threshold: Centrifugal barriers and channel competition 
1999Photodissociation dynamics of gas-phase BrICl sup - /sup and IBr sub 2 /sub sup - /sup anions 
1998Incoherent control of photodissociation pathways in I sub 2 /sub sup - /sup cluster ions 
1998Photochemistry of (OCS) sub n /sub sup - /sup cluster ions 
1998Photodissociation of I sub 2 /sub sup - /sup (OCS) sub n /sub cluster ions: Structural implications 
1998Transient solvent dynamics and incoherent control of photodissociation pathways in I sup - /sup sub 2 /sub cluster ions 
1998Electronic structure of (CS sub 2 /sub ) sub 2 /sub sup - /sup 
1997Collision-Induced Dissociation of Highly Excited NO sub 2 /sub in the Gas Phase and on MgO (100) Surfaces 
1997Photofragment imaging of HNCO decomposition: Angular anisotropy and correlated distributions 
1997Photodissociation of HNCO: Three competing pathways 
1996Competitive photodissociation channels in jet-cooled HNCO: Thermochemistry and near-threshold predissociation 
1996Unimolecular decomposition of NO sub 3 /sub : The NO+O sub 2 /sub threshold regime 
1996Molecular beams studies of the dissociation of highly excited NO sub 2 /sub induced by molecular colliders 
1995Inelastic scattering of NO( sup 2 /sup Π) with atomic and molecular colliders. Rotational and fine-structure excitations 
1995Resonances and fluctuations in the unimolecular reaction of NO sub 2 /sub 
1995General discussion 
1995Fully quantum-state resolved study of NO sub 2 /sub photodissociation. Correlated NO( sup 2 /sup Π sub Ω /sub , ν = 0 J,A) + O( sup 3 /sup P sub j /sub ) distributions 
1995Dissociation of highly excited NO sub 2 /sub induced by collisions with Ar, CO, and O sub 2 /sub 
1994Gas-phase collision-induced dissociation of highly excited NO sub 2 /sub 
1992Thermal diffusion effect on the relaxation rate of induced optical response of metal films of varying thickness excited by ultrashort laser pulses 
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