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Jeanne Pemberton, PhD, is a household name in chemistry departments across the country. Her research on surface vibrational spectroscopy has enabled fundamental advances in the field of analytical chemistry.In her 25 years at The University of Arizona, Pemberton has received more than 40 research grants. Among the many boards and committees she serves, she was the chair of the Math and Physical Sciences Advisory Committee at the National Science Foundation in 2004. In addition to receiving the College of Science Distinguished Teaching Award, she has also received the distinguished American Chemical Society Award for Excellence in Analytical Chemistry, which is among the highest honors in her field.Dr. Pemberton’s group research seeks to develop an understanding of chemistry in several technologically important areas including electrochemistry and electrochemically-related devices, chromatography, self-assembled monolayers, surfactant systems, and environmental and atmospheric systems. Methodologies employed for these efforts include surface vibrational spectroscopies, near-field optical methods, electrochemistry, x-ray photoelectron spectroscopy, Auger electron spectroscopy, LEED, work function measurements, ellipsometry, electron microscopy, and the scanning probe microscopies AFM and STM. Molecular nanoscale imaging exists prominently in the ability to elucidate structural and mechanistic details of surface and interfacial chemistry.Two images of transient intermediate states on NaCl in its reaction with the mineral acids, HNO3 and H2SO4, are shown below. These transient structures are formed en route to the final surface products of crystalline NaNO3 and NaHSO4, respectively.Specific interfacial systems of interest include electrochemical battery and electroluminescent and electrochromic devices, models of these devices fabricated and studied in ultrahigh vacuum, organized molecular assemblies at solid surfaces or air-water interfaces formed spontaneously or by self-assembly or Langmuir-Blodgett techniques, chromatography stationary phase systems, soil and mineral systems important in the fate and transport of environmentally important chemicals, and surfaces such as ice, mineral acids, and alkali halides important in atmospheric processes.
Courses
  • EC
    Electroanalytical Chemistry

  • MSM
    Methods of Surface and Materials Analysis

  • AS
    Analytical Spectroscopy

  • AAC
    Advanced Analytical Chemistry Laboratory

Student Thesis/Dissertation
  • A Chemoenzymatic Approach to Stereospecific Green Synthesis of Rhamnolipid Biosurfactants

    2022

    masters
  • Spectroscopic Investigations of Organic Semiconductor Thin Film Stabilities

    2021

    doctoral
  • Synthesis and Characterization of Bio-inspired Glycolipid Surfactants

    2018

    doctoral
  • Surface, Aggregation, and Phase Characterization of Microbially-Produced & Chemically-Synthesized Monorhamnolipids

    2017

    doctoral
  • Polarization Modulated-Infrared Reflectance Absorbance Spectroscopy Of Orientation And Binding Mode Of Pentafluorobenzyl Acid Modifiers On Indium Zinc Oxide

    2015

    masters
  • Flow Field Penetration in Thin Nanoporous Polymer Films under Laminar Flow by Förster Resonance Energy Transfer Coupled with Total Internal Reflectance Fluorescence Microscopy

    2015

    doctoral
  • Spectroscopy Investigation of Molecular Processes at Organic/Metal Oxide and Organic/Metal Interfaces in Organic Photovoltaic Devices

    2015

    doctoral
Grants
  • Funding agency logo
    Degradation of Organic Semiconductors: Functional and Mechanistic Descriptions from Macroscale to Nanoscale

    Principal Investigator (PI)

    2020

    $670.2K
    Active
  • Funding agency logo
    CAS: Glyonic Liquids: Sugar-Based Ionic Liquids & Deep Eutectic Solvents from Sustainable Sources for Electrochemical Applications

    Principal Investigator (PI)

    2020

    $570.0K
    Active
  • Funding agency logo
    Degradation of Organic Semiconductors: Functional and Mechanistic Descriptions from Macroscale to Nanoscale

    Principal Investigator (PI)

    2020

    $20.8K
    Active
  • Funding agency logo
    Degradation of Organic Semiconductors: Functional and Mechanistic Descriptions from Macroscale to Nanoscale

    Principal Investigator (PI)

    2020

    $59.5K
  • Funding agency logo
    In Operando Characterization of Degradation Processes in Organic Semiconductor Materials

    Principal Investigator (PI)

    2016

    $590.0K
  • Funding agency logo
    NSMDS: Molecular Design, Synthesis and Characterization of Green Glycolipid Surfactants

    Principal Investigator (PI)

    2013

    $4.5M
  • Funding agency logo
    MRI: Acquisition of a Multi-Functional Scanning Probe Microscope System for Nanoscale Surface and Interface Characterization

    Co-Investigator (COI)

    2013

    $317.4K
  • Funding agency logo
    Structure & Dynamics of Solvent Layers at Polymer Interfaces: The Role of Molecular Interactions

    Co-Investigator (COI)

    2010

    $196.3K
  • Funding agency logo
    Center for Interface Science, Hybrid Solar- Electric Materials (CIS:HSEM)

    Co-Investigator (COI)

    2009

    $13.0M
  • Funding agency logo
    Correlation of Molecular Architecture and Fluid Dynamic Properties within Solid-Fluid Interfaces

    Principal Investigator (PI)

    2009

    $596.4K
Technologies / Patents
      News
      • Organic Semiconductor Research Could Boost Electronics

        2016

      • UA Research goes from Idea to Patent to Market

        2015

      • From Grad School to Startup

        2014

      • Catapulting UA Discoveries to the World

        2014

      • Two UA Students Earn Goldwater Scholarships

        2013

      • UA Undergraduate Receives $10,000 From Astronaut Scholarship Foundation

        2013

      • DOE to Establish Energy Frontier Research Center at UA

        2009

      • AAAS Names Nine From UA to Fellows

        2009

      • Interdisciplinary UA, NAU Team Receives $3.3 million to Study Biosurfactants

        2007

      • Pillars of Excellence Reception to be Held March 1

        2007

      • Professors, Students to be Honored at BookStore Reception

        2006

      • New UA Regents' Professors Honored

        2005

      • President Likins Nominates Six to be Regents' Professors

        2005

      • Learning How To Erase Electronic Paper

        2004

      Publications (207)
      Recent
      • Optical Spectroscopy of Surfaces, Interfaces, and Thin Films

        2021

      • Interfacial and Solution Aggregation Behavior of a Series of Bioinspired Rhamnolipid Congeners Rha-C14-Cx x 6, 8, 10, 12, 14)

        2021

      • Lyotropic Phase Behavior of Alkyl Thioglycolipid Surfactants: Effects of Sugar Headgrouand Alkyl Chain Length

        2021

      • FTIR Spectroelectrochemistry of F4TCNQ Reduction Products and Their Protonated Forms

        2020

      • Optimization of a Chemical Synthesis for Rhamnolipids

        2020

      • A Classical Molecular Dynamics Simulation Study of Interfacial and Bulk Solution Aggregation Properties of Dirhamnolipids

        2020

      • The Addition of Executive Editors: A Change for the Better!

        2020

      • Biodegradability and Toxicity of Cellobiosides and Melibiosides

        2020

      • Thermally Induced Formation of HF4TCNQ- in F4TCNQ-doped Regioregular P3HT

        2020

      • Biodegradability and toxicity of monorhamnolipid biosurfactant diastereomers

        2019

      • Chemical Additives Enable Native Mass Spectrometry Measurement of Membrane Protein Oligomeric State within Intact Nanodiscs

        2019

      • Stability of Charge Transfer States in F4TCNQ-doped P3HT

        2019

      • Penetration and Reaction Depths of Vapor Deposited Ag, Mg, Al and Ca on Oligothiophene Thin Films

        2019

      • Direct Nanoscopic Measurement of Laminar SliFlow Penetration of Deformable Polymer Brush Surfaces: Synergistic Effect of Grafting Density and Solvent Quality

        2019

      • Stability of push-pull small molecule donors for organic photovoltaics: spectroscopic degradation of acceptor endcaps on benzo[1,2-b: 4,5-b’]dithiophene cores

        2019

      • Optical Spectroscopy of Surfaces, Interfaces, and Thin Films: A Status Report

        2019

      • Chemistry at the Interface of -Sexithiophene and Vapor Deposited Ag, Al, Mg, and Ca: A Molecular View

        2019

      • Unraveling the Differential Aggregation of Anionic and Nonionic Monorhamnolipids at the Interfaces: A Classical Molecular Dynamics Simulation Study

        2018

      • Molecular Dynamics Simulation of the Oil Sequestration Properties of a Nonionic Rhamnolipid

        2018

      • Correlation of Coexistent Charge Transfer States in F4TCNQ-Doped P3HT with Microstructure

        2018

      • Synthesis and Characterization of Four Diastereomers of Monorhamnolipids

        2017

      • Evolution of aggregate structure in solutions of anionic monorhamnolipids: experimental and computational results

        2017

      • Structural Properties of Nonionic Monorhamnolipid Aggregates in Water Studied by Classical Molecular Dynamics Simulations

        2017

      • Rhamnolipid Biosurfactants Preferentially Complex Rare Earth Elements

        2017

      • Effect of Solvent Quality on Laminar SliFlow Penetration of Poly(N-isopropylacrylamide) Films with an Exploration of Mass Transport Mechanism

        2017

      • Phosphonic Acids for Interfacial Engineering of Transparent Conductive Oxides

        2016

      • Preparation of S-Glycoside Surfactants and Cysteine Thioglycosides

        2016

      • Alkyl-melibioside and Alkyl-cellobioside Solution Phase Properties: Effect of Sugar Headgrouand Alkyl Chain Length on Surfactant Performance

        2016

      • Unexpected Chemistry at the Interface of alpha-Sexithiophene and Vapor Deposited Ag, Al, Mg, and Ca

        2016

      • Effect of Time and Deposition Method on Quality of Phosphonic Acid Modifier Self-assembled Monolayers on Indium Zinc Oxide

        2016

      • Understanding the Reaction Chemistry of 2,2′:5′,2′′-Terthiophene Films with Vapor Deposited Ag, Al and Ca

        2015

      • Flow Field Penetration in Thin Nanoporous Polymer Films under Laminar Flow by Förster Resonance Energy Transfer Coupled with Total Internal Reflectance Fluorescence Microscopy

        2015

      • PM-IRRAS Determination of Molecular Orientation of Phosphonic Acid Self-Assembled Monolayers on Indium Zinc Oxide

        2015

      • The Scope of Analytical Chemistry

        2015

      • Signature Vibrational Bands for Defects in CVD Single Layer Graphene by Surface Enhanced Raman Spectroscopy

        2015

      • Study of the C60/Ag Interface of a Large Area Nanoarchitectured Ag Substrate using Surface Enhanced Raman Scattering

        2014

      • Effect of fatty acid substrate chain length on Pseudomonas aeruginosa ATCC 9027 monorhamnolipid yield and congener distribution

        2014

      • Combined Quenching Mechanism of Anthracene Fluorescence by Cetylpyridinium Chloride in Sodium Dodecyl Sulfate Micelles

        2014

      • Thickness, Composition, and Molecular Structure of Residual Thin Films Formed by Forced Dewetting of Ag from Glycerol/D2O Solutions

        2014

      • Interface Between C60 and Ag on Nanostructured Plasmonic Ag Gratings: A SERS Study

        2013

      • Effect of modular diffraction gratings on absorption in P3HT:PCBM layers

        2013

      • Deciphering the metal-C60 interface in optoelectronic devices: evidence for C60 reduction by vapor deposited Al

        2013

      • A PM-IRRAS investigation of monorhamnolipid orientation at the air-water interface

        2013

      • Orientation of phenylphosphonic acid self-assembled monolayers on a transparent conductive oxide: A combined NEXAFS, PM-IRRAS, and DFT study

        2013

      • Reaction of thin films of solid-state benzene and pyridine with calcium

        2012

      • Fatty acid cosubstrates provide β-oxidation precursors for rhamnolipid biosynthesis in pseudomonas aeruginosa, as evidenced by isotope tracing and gene expression assays

        2012

      • Minimally competent lewis acid catalysts: Indium(III) and bismuth(III) salts produce rhamnosides 6-deoxymannosides) in high yield and purity

        2012

      • Reaction chemistry of solid-state pyridine thin films with Vapor deposited Ag, Mg, and Al

        2012

      • Analytical chemistry is alive and well all over Africa!

        2012

      • Raman spectroscopy of the reaction of thin films of solid-state benzene with vapor-deposited Ag, Mg, and Al

        2011

      • Fabrication of colloidal arrays by self-assembly of sub-100nm silica particles

        2011

      • Semi-transparent metal nanostructures as alternatives to transparent conducting oxides in organic photovoltaic devices

        2011

      • Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices

        2011

      • Self-Organized Thin Films of Hydrogen-Bonded Phthalocyanines: Characterization of Structure and Electrical Properties on Nanometer Length Scales

        2010

      • Comparison of a fluorinated aryl thiol self-assembled monolayer with its hydrogenated counterpart on polycrystalline Ag substrates

        2010

      • Evaporative deposition patterns of bacteria from a sessile drop: Effect of changes in surface wettability due to exposure to a laboratory atmosphere

        2010

      • Cadmium effects on transcriptional expression of rhlB/rhlC genes and congener distribution of monorhamnolipid and dirhamnolipid in Pseudomonas aeruginosa IGB83

        2010

      • Synthesis of uniform, spherical sub-100nm silica particles using a conceptual modification of the classic LaMer model

        2010

      • Tuning the Effective Work Function of Gold and Silver using Alkanethiols: Varying Surface Composition Through Dilution and Choice of Terminal Groups

        2009

      • Passivation of pinhole defect microelectrode arrays in ultrathin silica films immobilized on gold substrates

        2009

      • Surface raman spectroscopy of chemistry at the tris(8-hydroxyquinoline) aluminum/Ca interface

        2009

      • Investigation of interfacial interactions of solid-state benzene with low work function metals by Raman spectroscopy and mass spectrometry

        2009

      • Colloidal Polymerization of Polymer Coated Ferromagnetic Nanoparticles into Cobalt Oxide Nanowires

        2009

      • Surface Raman spectroscopy of the interface of tris-8-hydroxyquinoline) aluminum with Mg

        2009

      • Infrared reflectance-absorbance spectroscopy of thin films formed by forced dewetting of solid-fluid interfaces

        2008

      • Phosphonic Acid Modification of Indium-Tin Oxide Electrodes: Combined XPS/UPS/Contact Angle Studies

        2008

      • Efficient purification of the biosurfactant viscosin from Pseudomonas libanensis strain M9-3 and its physicochemical and biological properties

        2008

      • Investigation of the interfaces of tris-8-hydroxyquinoline) aluminum with Ag and Al using surface Raman spectroscopy

        2008

      • Interfacial structure in thin water layers formed by forced dewetting on self-assembled monolayers of omega-terminated alkanethiols on Ag

        2008

      • Spectroscopic investigation of uranyl(VI) and citrate coadsorption to Al sub 2 sub O sub 3 sub

        2008

      • Structure-function relationships in high-density docosylsilane bonded stationary phases by Raman spectroscopy and comparison to octadecylsilane bonded stationary phases: effects of aromatic compounds

        2008

      • Reduction of nitric acid on Ag in ultrahigh vacuum: A Raman spectroscopic investigation

        2008

      • Modification of Indium-Tin Oxide Electrodes with Thiophene Copolymer Thin Films: Optimizing Electron Transfer to Solution Probe Molecules

        2007

      • Electrospray ionization of uranyl-citrate complexes: Adduct formation and ion-molecule reactions in 3D ion traand ion cyclotron resonance trapping instruments

        2007

      • Magnetic assembly and pyrolysis of functional ferromagnetic colloids into one-dimensional carbon nanostructures

        2007

      • Underpotential deposition of thallium, lead, and cadmium at silver electrodes modified with self-assembled monolayers of 3-mercaptopropyl) trimethoxysilane

        2007

      • Raman spectroscopy of glycerol/D sub 2 sub O solutions

        2007

      • Ultrathin silica films immobilized on gold supports: fabrication, characterization, and modification

        2007

      • Phase transition between two anhydrous modifications of NaHSO sub 4 sub mediated by heat and water

        2007

      • Modification of BaTiO3 Thin Films: Adjustment of the Effective Surface Work Function

        2007

      • Magnetic Assembly of Functionalized Ferromagnetic Colloids as Templates for 1-D Ordered Mesostructures

        2007

      • Ions generated from uranyl nitrate solutions by electrospray ionization ESI) and detected with Fourier transform ion-cyclotron resonance FT-ICR) mass spectrometry

        2006

      • Structure-function relationships in high-density docosylsilane bonded stationary phases by Raman spectroscopy and comparison to octadecylsilane bonded stationary phases

        2006

      • Effects of Pressurized Solvent Environments on the Alkyl Chain Order of Octadecylsilane Stationary Phases by Raman Spectroscopy

        2006

      • Determination of the acid dissociation constant of the biosurfactant monorhamnolipid in aqueous solution by potentiometric and spectroscopic methods

        2006

      • Raman spectral conformational order indicators in perdeuterated alkyl chain systems

        2006

      • Effect of Aqueous Subphase Metal Ion on the Structure of Rhamnolipid at the Air-Water Interface

        2005

      • In situ adsorption studies of 1-octanol on silica surfaces by ATR-FTIR

        2005

      • Raman spectroscopic study of the conformational order of octadecylsilane stationary phases: effects of electrolyte and pH

        2005

      • Alkylsilane-based stationary phases via a displaceable surface template approach: synthesis, characterization, and chromatographic performance

        2005

      • Erratum: Raman spectroscopy of the reaction of sodium chloride with nitric acid: Sodium nitrate growth and effect of water exposure J. Phys. Chem. A 2001) 105 3788-3795)

        2004

      • Structure-function relationships in high-density octadecylsilane stationary phases by Raman spectroscopy. 4. Effects of neutral and basic aromatic compounds

        2003

      • Speciation and coordination chemistry of uranyl(VI)citrate complexes in aqueous solution

        2003

      • Model aluminum-poly(p-phenylenevinylene) interfaces studied by surface Raman spectroscopy

        2003

      • “Metal-Organic Interfaces in Organic Light-Emitting Devices OLEDs) Studied by Surface Raman Spectroscopy

        2003

      • Emersion of 11-mercapto-1-undecanol-modified Ag substrates from aqueous and nonaqueous solvents: The effect of emersion velocity on emersed solvent layer thickness

        2003

      • Quantitative correlation of Raman spectral indicators in determining conformational order in alkyl chains

        2002

      • Structure-function relationships in high-density octadecylsilane stationary phases by Raman spectroscopy. 2. Effect of common mobile-phase solvents

        2002

      • Structure-function relationships in high-density octadecylsilane stationary phases by Raman spectroscopy. 1. Effects of temperature, surface coverage, and preparation procedure

        2002

      • Insulating ultrathin silica films formed by a room-temperature sol-gel process

        2001

      • Raman spectroscopy of octadecylsilane stationary phase conformational order: Effect of solvent

        2001

      • Novel silicon dioxide sol-gel films for potential sensor applications: a surface plasmon resonance study

        2001

      • Vibrational spectroscopy of dimethylchlorooctadecylsilane covalently bonded to ultrathin silica films immobilized on Ag surfaces

        2001

      • Raman spectroscopy of the reaction of sodium chloride with nitric acid: Sodium nitrate growth and effect of water exposure

        2001

      • Segregation of NaBr in NaBr/NaCl crystals grown from aqueous solutions: Implications for sea salt surface chemistry

        2001

      • Covalent surface chemical modification of electrodes for cardiac pacing applications

        2000

      • Sequestration of carbonaceous species within alkanethiol self-assembled monolayers on Ag by Raman spectroscopy

        2000

      • Raman spectroscopy of model membrane monolayers of dipalmitoylphosphatidic acid at the air-water interface using surface enhancement from buoyant thin silver films

        2000

      • Adsorption interactions of aromatics and heteroaromatics with hydrated and dehydrated silica surfaces by raman and FTIR spectroscopies

        2000

      • Raman spectroscopy and atomic force microscopy of the reaction of sulfuric acid with sodium chloride

        2000

      • Dual-wavelength resonance Raman spectroscopy of polydiacetylene monolayers on Au surfaces

        2000

      • Electrochemical cleaning of surface-confined carbon contamination in self-assembled monolayers on polycrystalline Ag and Au

        2000

      • Surface vibrational spectroscopy of alkylsilane layers covalently bonded to monolayers of 3-mercaptopropyl)trimethoxysilane on Ag substrates

        2000

      • Challenges for the analytical chemistry curriculum

        2000

      • Nanochannel Electrodes Fabricated on Silica-Passivated Metals Using Scanning Probe Lithography

        2000

      • Determination of Surface Coverage of an Adsorbate on Silica Using FTIR Spectroscopy

        1999

      • Surface Raman scattering of interfaces at Ag electrodes emersed from dimethylsulfoxide: Spectroscopic evidence for an emersion-induced potential shift

        1999

      • Surface enhancement factors for Ag and Au surfaces relative to Pt surfaces for monolayers of thiophenol

        1999

      • Effects of Electrolyte and Potential on the in Situ Structure of Alkanethiol Self-Assembled Monolayers on Silver

        1999

      • Investigation of trace interfacial water at silver electrodes in a series of normal alcohols using surface enhanced Raman scattering

        1999

      • Interfacial structure of dimethylsulfoxide at Ag electrodes from surface enhanced Raman scattering and differential capacitance

        1999

      • Electrochemical and surface enhanced Raman scattering studies of bromide ion adsorption at silver electrodes in a series of normal alcohols

        1999

      • Determination of emersed electrochemical interface thickness by ellipsometry: Aqueous electrolytes on Ag

        1998

      • In situ monitoring of the NaCl HNO sub 3 sub surface reaction: The observation of mobile surface strings

        1998

      • Alkyl chain conformation of octadecylsilane stationary phases by Raman spectroscopy. 1. Temperature dependence

        1998

      • Air stability of alkanethiol self-assembled monolayers on silver and gold surfaces

        1998

      • Orientation of 1- and 2-methylimidazole on silver electrodes determined with surface-enhanced raman scattering

        1998

      • Raman spectroscopy and vibrational assignments of 1- and 2-methylimidazole

        1997

      • In Situ Electrochemistry of Ru(NH sub 3 sub su3+ su sub 6 sub in a Perfused Rat Heart

        1997

      • Raman spectroscopy of Langmuir monolayers at the air-water interface

        1997

      • Characterization of Octadecylsilane Stationary Phases on Commercially Available Silica-Based Packing Materials by Raman Spectroscopy

        1997

      • Hydrolysis and condensation of self-assembled monolayers of 3-mercaptopropyl)trimethoxysilane on Ag and Au surfaces

        1997

      • Carbon Contamination at Silver Surfaces: Surface Preparation Procedures Evaluated by Raman Spectroscopy and X-ray Photoelectron Spectroscopy

        1996

      • Surface Enhanced Raman Scattering: A Continuum of Possibilities

        1996

      • Spectroscopic methods for the characterization of electrochemical interfaces and surfaces

        1996

      • Interfacial solvent structure in butan-1-ol, butan-2-ol and 2-methylpropan-1-ol at Au and Ag electrodes from surface enhanced Raman scattering and capacitance measurements

        1996

      • Wavelength Calibration of Multipurpose Multichannel Raman Spectrometers. Part II: Calibration Standards and Calibration Fit Considerations

        1995

      • Thin sol-gel silica films on 3-mercaptopropyl)trimethoxysilane-modified Ag and Au surfaces

        1995

      • Characterization of octadecylsilane and stearic acid layers on Al2O3 surfaces by Raman spectroscopy

        1995

      • Wavelength Calibration of Multipurpose Multichannel Raman Spectrometers. Part I: Instrumental Factors Affecting Precision

        1995

      • Raman spectroscopy of covalently bonded alkylsilane layers on thin silica films immobilized on silver substrates

        1994

      • Water and electrolyte structure at Ag electrodes in nonaqueous butanol solutions using surface-enhanced Raman scattering

        1994

      • In situ Raman spectroscopy of aza-arenes adsorbed at the aqueous/silica interface

        1994

      • Surface Raman scattering of the butanol isomers on emersed Ag and Au electrodes

        1993

      • Surface Raman scattering of self-assembled monolayers of 3-mercaptopropyl)trimethoxysilane on silver: Orientational effects of hydrolysis and condensation reactions

        1993

      • Investigation of the quenching of surface enhanced Raman scattering from pyridine on copper and silver electrodes by underpotential deposition of lead

        1992

      • Women in science: The response 16]

        1992

      • Raman scattering from monolayer films of thiophenol and 4-mercaptopyridine at Pt surfaces

        1992

      • A simple method for determination of orientation of adsorbed organics of low symmetry using surface-enhanced Raman scattering

        1992

      • Surface enhanced Raman scattering investigation of interfacial structure at Ag electrodes in electrolyte solutions of the isomers of butanol

        1992

      • Surface Raman scattering of organic thin films on transition metal surfaces

        1992

      • Determination of alcohol solvent orientation and bonding at silver electrodes using surface-enhanced Raman scattering: methanol, ethanol, 1-propanol, and 1-pentanol

        1992

      • Comparison of charge transfer enhancement in the surface enhanced Raman scattering of pyridine on copper and silver electrodes

        1992

      • Surface-enhanced Raman scattering of the acid-base forms of imidazole on Ag

        1992

      • Raman spectroscopy of the emersed Ag alcohol electrochemical interface

        1991

      • Sol-Gel Synthesis and Characterization of Barium Polytitanates in the BaO-TiO2 System

        1991

      • Raman spectroscopy of calcium phosphate glasses with varying CaO modifier concentrations

        1991

      • A complete experimental assessment of Franck-Condon structural effects for an irreversible outer-sphere electron-transfer reaction: Applications of time-dependent Raman scattering theory to the one-electron reduction of 4-cyano-N-methylpyridinium

        1991

      • Surface Raman Scattering of Self-Assembled Monolayers Formed from 1-Alkanethiols: Behavior of Films at Au and Comparison to Films at Ag

        1991

      • Surface Raman scattering of self-assembled monolayers formed from 1-alkanethiols at Ag

        1991

      • Surface Raman scattering of methanol, 1-propanol, 1-pentanol, and 1-butanethiol on in situ and emersed silver electrodes

        1990

      • Optical properties of selected first-row transition metals determined by reflection electron energy loss spectroscopy

        1990

      • Raman Spectroscopy with Charge-Coupled Device Detection

        1990

      • Differential reflectance spectroscopy and SERS of mildly roughened silver electrodes

        1990

      • Structural Evolution of Chemically-Derived Barium Tetratitanate BaTi4O9) Powders

        1990

      • Optical constants of the noble metals determined by reflection electron energy loss spectroscopy

        1990

      • Optical properties of metal surfaces from electron energy loss spectroscopy in the reflection mode

        1990

      • Effect of charge traps on Raman spectroscopy using a Thomson-CSF charge coupled device detector

        1990

      • SERS investigation of interfacial methanol at silver electrodes

        1990

      • Surface Enhanced Fluorescence of Basic Fuchsin at Roughened Silver Electrodes

        1989

      • Raman spectroscopy with helium-neon laser excitation and Charge-Coupled Device detection

        1989

      • Comparison of Supramolecular Structure and Spectroscopic Photoelectrochemical Properties of Tetravalent and Trivalent Metal Phthalocyanine Thin Films

        1989

      • EFFECTS OF LASER ILLUMINATION DURING CONTROLLED-RATE

        1988

      • Surface enhanced Raman scattering in electrochemical systems: The complex roles of surface roughness

        1988

      • XPS CHARACTERIZATION OF A COMMERCIAL Cu/ZnO/ Al/2O/3 CATALYST: EFFECTS OF OXIDATION, REDUCTION AND THE STEAM REFORMATION OF METHANOL.

        1988

      • Laser-induced thermal decay of pyridine and chloride surface-enhanced Raman scattering as a probe of silver surface-active sites

        1988

      • INTERPRETATION OF SERS INTENSITY-LEAD COVERAGE PROFILES FOR PYRIDINE AND CHLORIDE ION IN TERMS OF ELECTROMAGNETIC ENHANCEMENT AND CHARGE-TRANSFER EXCITATION.

        1987

      • SERS investigation of interfacial Pb(II) species in weakly acidic aqueous halide media

        1987

      • Surface-enhanced Raman scattering of HCN at Pb-modified Ag surfaces

        1987

      • CONTRIBUTIONS OF ATOMIC-SCALE ROUGHNESS AND ADSORBATE COVERAGE TO THE QUENCHING OF THE SERS RESPONSE AT LEAD-MODIFIED SILVER ELECTRODES.

        1987

      • Electrochemical and SEM characterization of Ag electrodes roughened by potential sweeand potential steprocesses in aqueous chloride and chloride pyridine media

        1987

      • Effects of solution conditions on the surface-enhanced Raman scattering of cyanide species at Ag electrodes

        1987

      • EFFECT OF UNDERPOTENTIALLY DEPOSITED LEAD ON THE SERS OF CHLORIDE, BROMIDE, AND THIOCYANATE ADSORBED AT SILVER ELECTRODES: EVIDENCE FOR CHEMICAL CONTRIBUTIONS TO SERS.

        1987

      • Surface enhanced Raman scattering of pyridine on Ag electrodes formed with controlled-rate oxidation-reduction cycles

        1987

      • Effect of meso substituents on exchange-coupling interactions in μ-oxo iron(III) porphyrin dimers

        1986

      • SERS AND SEM OF ROUGHENED SILVER ELECTRODE SURFACES FORMED BY CONTROLLED OXIDATION-REDUCTION IN AQUEOUS CHLORIDE MEDIA.

        1986

      • TIME DEPENDENCE OF SURFACE ENHANCED RAMAN SCATTERING AT SILVER IN THE PRESENCE OF UNDERPOTENTIALLY DEPOSITED LEAD AND ITS IMPLICATIONS FOR THE ROLES OF SURFACE ROUGHNESS.

        1985

      • The effect of underpotentially deposited Pb on the surface enhanced Raman scattering ability of polycrystalline Ag

        1985

      • Surface enhanced Raman scattering at Ag electrodes in non-aqueous pyridine solutions

        1985

      • Investigation of the Ag Electrode/Solution Interface in Aqueous and Nonaqueous Electrochemical Systems with Surface Enhanced Raman Scattering

        1985

      • INVESTIGATION OF THE ROLE OF SURFACE ELECTRONIC STRUCTURE IN SURFACE ENHANCED RAMAN SCATTERING IN ELECTROCHEMICAL SYSTEMS.

        1984

      • SERS from thin Ag films electrochemically deposited onto Pt electrodes

        1984

      • Dithizone adsorption at metal electrodes. 5. Voltammetric and surface raman spectroelectrochemical investigation at a gold electrode

        1983

      • Dithizone adsorption at metal electrodes. 7. Preliminary characterization of adsorption kinetics using surface raman spectroelectrochemistry at a rotating disk silver electrode

        1982

      • Dithizone adsorption at metal electodes. Electrochemical characterization of dithizone anion at a silver electrode

        1982

      • Raman Spectroscopic Investigation of the Acid-Base Forms of Dithizone

        1982

      • X-ray photoelectron spectroscopic investigation of dithizone anion adsorption at silver and copper electrodes

        1982

      • Dithizone adsorption at metal electrodes. 4. Voltammetric and surface Raman spectroelectrochemical investigation at a copper electrode

        1982

      • Quantitation of Adsorption Parameters and Adsorption Rates for Dithizone Anion Adsorption at Ag Using Surface Enhanced and Resonance Enhanced Raman Spectroscopy

        1982

      • Dithizone adsorption at metal electrodes. 2. Raman spectroelectrochemical investigation of effect of applied potential at a silver electrode

        1981

      • Detection of low concentrations of a colored adsorbate at silver by surface-enhanced and resonance-enhanced Raman spectrometry

        1981

      • ROTATING DISK CELL FOR RAMAN SPECTROELECTROCHEMISTRY: INVESTIGATION OF AN ELECTRODE SURFACE SPECIES AND AN ELECTROGENERATED SOLUTION SPECIES.

        1981

      • Reactions of cation radicals of EE systems. 10. The influence of ion association on cation radical disproportionation

        1980

      • Reactions of cation radicals of EE systems. 9. Kinetics and mechanism of the reaction of thianthrene cation radical with nitrate ion

        1979

      • Small Volume, High Performance Cell for Nonaqueous Spectroelectrochemistry

        1977

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